A new form of pure, solid carbon has been synthesized consisting of a somewhat disordered hexagonal close packing of soccer-ball-shaped C60 molecules. Infrared spectra and X-ray diffraction studies of the molecular packing confirm that the molecules have the anticipated 'fullerene' structure. Mass spectroscopy shows that the C70 molecule is present at levels of a few per cent. The solid-state and molecular properties of C60 and its possible role in interstellar space can now be studied in detail.
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References
Rohlfing, E. A., Cox, D. M. & Kaldor, A. J. chem. Phys. 81, 3322–3330 (1984).
Kroto, H. W., Heath, J. R., O'Brien, S. C., Curl, R. F. & Smalley, R. E. Nature 318, 162–163 (1985).
Zhang, Q. L. et al. J. phys. Chem. 90, 525–528 (1986).
Liu, Y. et al. Chem. Phys. Lett. 126, 215–217 (1986).
Newton, M. D. & Stanton, R. E. J. Am. chem. Soc. 108, 2469–2470 (1986).
Lüthi, H. P. & Almlöf, J. Chem. Phys. Lett. 135, 357–360 (1987).
Satpathy, S. Chem. Phys. Lett. 130, 545–550 (1986).
Haddon, R. C., Brus, L. E. & Raghavachari, K. Chem. Phys. Lett. 125, 459–464 (1986).
Larsson, S., Volosov, A. & Rosén, A. Chem. Phys. Lett. 137, 501–504 (1987).
Wu, Z. C., Jelski, D. A. & George, T. F. Chem. Phys. Lett. 137, 291–294 (1987).
Stanton, R. E. & Newton, M. D. J. phys. Chem. 92, 2141–2145 (1988).
Weeks, D. E. & Harter, W. G. Chem. Phys. Lett. 144, 366–372 (1988).
Weeks, D. E. & Harter, W. G. J. chem. Phys. 90, 4744–4771 (1989).
Elser, V. & Haddon, R. C. Nature 325, 792–794 (1987).
Slanina, Z. et al. J. molec. Struct. 202, 169–176 (1989).
Fowler, P. W., Lazzeretti, P. & Zanasi, R. Chem. Phys. Lett. 165, 79–86 (1990).
Haddon, R. C. & Elser, V. Chem. Phys. Lett. 169, 362–364 (1990).
Kroto, H. Science 242, 1139–1145 (1988).
Kroto, H. W. in Polycyclic Aromatic Hydrocarbons and Astrophysics (eds Léger, A. et al.) 197–206 (Reidel, Dordrecht, 1987).
Léger, A., d'Hendecourt, L., Verstraete, L. & Schmidt, W. Astr. Astrophys. 203, 145–148 (1988).
Krätschmer, W., Fostiropoulos, K. & Huffman, D. R. in Dusty Objects in the Universe (eds Bussoletti, E. & Cittone, A. A.) (Kluwer, Dordrecht, in the press).
Krätschmer, W., Fostiropoulos, K. & Huffman, D. R. Chem. Phys. Lett. 170, 167–170 (1990).
Steffens, P., Niehuis, E., Friese, T. & Benninghoven, A. Ion Formation from Organic Solids (ed. Benninghoven, A.) Ser. chem. Phys. Vol. 25, 111–117 (Springer-Verlag, New York, 1983).
Kroto, H. W. Nature 329, 529–531 (1987).
Schmalz, T. G., Seitz, W. A., Klein, D. J. & Hite, G. E. J. Am. chem. Soc. 110, 1113–1127 (1988).
Hendricks, S. B., Jefferson, M. E. & Schultz, J. F. Z. Kristallogr. 73, 376–380 (1930).
Edwards, O. S., Lipson, H. & Wilson, A. J. C. Nature 148, 165 (1941).
Edwards, O. L. & Lipson, H. Proc. R. Soc. A180, 268–277 (1942).
Houska, C. R., Averbach, B. L. & Cohen, M. Acta Metal. 8, 81–87 (1960).
Heath, J. R., Curl, R. F. & Smalley, R. E. J. chem. Phys. 87, 4236–4238 (1987).
Huffman, D. R. Adv. Phys. 26, 129–230 (1977).
Herbig, E. Astrophys. J. 196, 129–160 (1975).
Léger, A. & Puget, J. L. Astr. Astrophys. Lett. 137, L5–L8 (1984).
Allamandola, L. J., Tielens, A. G. & Barker, J. R. Astrophys. J. 290, L25–L28 (1985).
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Krätschmer, W., Lamb, L., Fostiropoulos, K. et al. Solid C60: a new form of carbon. Nature 347, 354–358 (1990). https://doi.org/10.1038/347354a0
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DOI: https://doi.org/10.1038/347354a0