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. 2022 Mar 4;15(5):1929.
doi: 10.3390/ma15051929.

The Effect of Surface Substrate Treatments on the Bonding Strength of Aluminium Inserts with Glass-Reinforced Poly(phenylene) Sulphide

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The Effect of Surface Substrate Treatments on the Bonding Strength of Aluminium Inserts with Glass-Reinforced Poly(phenylene) Sulphide

Ashish Matta et al. Materials (Basel). .

Abstract

Materials composed of a polymer matrix reinforced with carbon/glass fibres providing lightweight and superior mechanical properties are widely used as structural components for automotive and aerospace applications. However, such parts need to be joined with various metal alloys to obtain better mechanical performance in many structural elements. Many studies have reported enhancements in polymer-metal bonding using adhesives, adhesive/rivet combined joints, and different surface treatments. This study investigated the influences of various surface treatments on the adhesion between glass-reinforced poly(phenylene) sulphide (PPS) and aluminium alloy during the injection over-moulding process. Adhesion strength was evaluated via the shear test. Correlations for the shear strength of the polymer-metal with different metal-substrate treatments were studied. Since the strongest bonding was attained in the treatment with the highest roughness, this value, as it determines the level of micromechanical interlocking of connected materials, seems to be a critical factor affecting the adhesion strength. Three-dimensional (3D) topographic images characterized with a 3D optical microscope indicated that there was a meaningful influence exerted by the interface topologies of the aluminium substrates used for the over-moulding process. The results further indicated that increases in a substrate's surface energy in connection with atmospheric plasma treatments negatively influence the final level of the bonding mechanism.

Keywords: PPS–aluminium bi-component; polymer–metal bonding; surface modification.

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Conflict of interest statement

The authors declare no conflict of interest.

Figures

Figure 1
Figure 1
Scheme for the atmospheric pressure plasma system by Diener Electronic [15].
Figure 2
Figure 2
Shear test specimen: (a) real picture—top view; (b) side-view sketch.
Figure 3
Figure 3
Scanning electron microscopy (SEM) images of the surfaces of the (a) untreated, (b) chemical 1, (c) chemical 2, (d) plasma, (e) sandblasting, and (f) sandblasting + plasma inserts.
Figure 4
Figure 4
Bonding strength vs. surface roughness.
Figure 5
Figure 5
Three-dimensional (3D) images of Al substrate surfaces obtained with a 3D optical microscope.
Figure 6
Figure 6
Bonding strength vs. contact angle.
Figure 7
Figure 7
Surface energy vs. bonding strength.

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