Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal-Organic Framework

doi:10.1021/jacs.8b09608

. 2018 Dec 12;140(49):16882-16887.

doi: 10.1021/jacs.8b09608. Epub 2018 Nov 28.

Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal-Organic Framework

Viktorija Glembockyte¹, Mathieu Frenette^{1

2}, Cristina Mottillo¹, Andrés M Durantini^{1

3}, Jeff Gostick⁴, Vjekoslav Štrukil^{1

5}, Tomislav Friščić^{1

5}, Gonzalo Cosa¹

Affiliations

¹ Department of Chemistry and Quebec Centre for Applied Materials (QCAM) , McGill University , 801 Sherbrooke Street W. , Montreal , Quebec H3A 0B8 , Canada.
² Department of Chemistry , Université du Québec à Montréal , Case postale 8888, Succursale Centre-Ville , Montreal , Quebec H3C 3P8 , Canada.
³ Departamento de Química, Facultad de Ciencias Exactas, Físico-Químicas y Naturales , Universidad Nacional de Río Cuarto , Ruta Nacional 36 Km 601 , X5804BYA Río Cuarto , Córdoba , Argentina.
⁴ Department of Chemical Engineering , McGill University , 3610 University Street , Montreal , Quebec H3A 0C5 , Canada.
⁵ Rud̵er Bošković Institute , Bijenička cesta 54 , 10000 Zagreb , Croatia.

PMID: 30462919
DOI: 10.1021/jacs.8b09608

Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal-Organic Framework

Viktorija Glembockyte et al. J Am Chem Soc. 2018.

. 2018 Dec 12;140(49):16882-16887.

doi: 10.1021/jacs.8b09608. Epub 2018 Nov 28.

Authors

Viktorija Glembockyte¹, Mathieu Frenette^{1

2}, Cristina Mottillo¹, Andrés M Durantini^{1

3}, Jeff Gostick⁴, Vjekoslav Štrukil^{1

5}, Tomislav Friščić^{1

5}, Gonzalo Cosa¹

Affiliations

¹ Department of Chemistry and Quebec Centre for Applied Materials (QCAM) , McGill University , 801 Sherbrooke Street W. , Montreal , Quebec H3A 0B8 , Canada.
² Department of Chemistry , Université du Québec à Montréal , Case postale 8888, Succursale Centre-Ville , Montreal , Quebec H3C 3P8 , Canada.
³ Departamento de Química, Facultad de Ciencias Exactas, Físico-Químicas y Naturales , Universidad Nacional de Río Cuarto , Ruta Nacional 36 Km 601 , X5804BYA Río Cuarto , Córdoba , Argentina.
⁴ Department of Chemical Engineering , McGill University , 3610 University Street , Montreal , Quebec H3A 0C5 , Canada.
⁵ Rud̵er Bošković Institute , Bijenička cesta 54 , 10000 Zagreb , Croatia.

PMID: 30462919
DOI: 10.1021/jacs.8b09608

Abstract

We report a strategy to synthesize highly emissive, photostable, microporous materials by solid-state entrapment of boron dipyrromethene (BODIPY) fluorophores in a metal-organic framework. Solvent-free mechanochemistry or accelerated aging enabled quantitative capture and dispersal of the PM605 dye within the ZIF-8 framework starting from inexpensive, commercial materials. While the design of emissive BODIPY solids is normally challenged by quenching in a densely packed environment, herein reported PM605@ZIF-8 materials show excellent emissive properties and to the best of our knowledge an unprecedented ∼10-fold enhancement of BODIPY photostability. Time-resolved and steady-state fluorescence studies of PM605@ZIF-8 show that interchromophore interactions are minimal at low dye loadings, but at higher ones lead to through-pore energy transfer between chromophores and to aggregate species.

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Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal-Organic Framework

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Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal-Organic Framework

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