Single crystals of the group IVa to VIII transition‐metal disilicides, namely TiSi2, VSi2, CrSi2, MoSi2, αFeSi2, and CoSi2, have been successfully grown by a floating‐zone method. Temperature and crystallographic dependencies of the resistivity have been measured in the temperature range from 4.2 K to room temperature. The resistivity of all the disilicides show a positive temperature dependence and some anisotropy. The thermal component of the resistivity changes systematically with the group number of the metal elements and correlates well with the d band density of states at the Fermi energy.

1.
See S. P. Murarka, Silicides for VLSI Applications (Academic, New York, 1983).
2.
D.
Shinoda
,
S.
Asanabe
, and
Y.
Sasaki
,
J. Phys. Soc. Jpn.
19
,
269
(
1964
).
3.
I.
Nishida
,
J. Mater. Sci.
7
,
435
(
1972
);
I.
Nishida
,
7
,
1119
(
1972
).,
J. Mater. Sci.
4.
U.
Birkholz
and
J.
Schelm
,
Phys. Status Solidi
27
,
413
(
1968
);
U.
Birkholz
and
J.
Naegele
,
Phys. Status Solidi
39
,
197
(
1970
).,
Phys. Status Solidi
5.
S. P.
Murarka
,
J. Vac. Sci. Technol.
17
,
775
(
1980
).
6.
S.
Sivaram
,
P. J.
Ficarola
, and
K. C.
Cadien
,
J. Appl. Phys.
58
,
1314
(
1985
).
7.
P. Villars and L. D. Calvert, Pearson’s Handbook of Crystallographic Data for Intermetallic Phases (American Society for Metals, Metals Park, OH, 1985).
8.
J.
Beaudouin
,
C. R. Acad. Sci. Paris, Ser. C
263
,
1065
(
1966
).
9.
O.
Thomas
,
R.
Madar
,
J. P.
Senateur
, and
O.
Laborde
,
J. Less‐Common Met.
136
,
175
(
1987
).
10.
F.
Nava
,
E.
Mazzega
,
M.
Michelini
,
O.
Laborde
,
O.
Thomas
,
J. P.
Senateur
, and
R.
Madar
,
J. Appl. Phys.
65
,
1584
(
1989
).
11.
O.
Thomas
,
J. P.
Senateur
,
R.
Madar
,
O.
Laborde
, and
E.
Rosencher
,
Solid State Commun.
55
,
692
(
1985
).
12.
O.
Laborde
,
O.
Thomas
,
J. P.
Senateur
, and
R.
Madar
,
J. Phys. F
16
,
1745
(
1986
).
13.
B. M.
Ditchek
,
J. Cryst. Growth
69
,
207
(
1984
).
14.
A.
Briggs
,
O.
Thomas
,
R.
Madar
, and
J. P.
Senateur
,
Appl. Surf. Sci.
38
,
88
(
1989
).
15.
H.
Tabata
and
T.
Hirano
,
J. Jpn. Inst. Metals
52
,
1154
(
1988
).
16.
T. B. Massalski, Ed., Binary Alloy Phase Diagrams (American Society for Metals, Metals Park, OH, 1986).
17.
Y.
Iye
,
T.
Tamegai
,
H.
Takeyama
, and
H.
Takei
,
Jpn. J. Appl. Phys.
27
,
L658
(
1988
).
18.
P. H.
Woerlee
,
P. M. Th.
van Attekum
,
A. A. M.
Hoeben
,
G. A. M.
Hurkx
, and
R. A. M.
Wolters
,
Appl. Phys. Lett.
44
,
876
(
1984
).
19.
J. W. C.
de Vries
and
A. H.
van Ommen
,
J. Appl. Phys.
64
,
749
(
1988
).
20.
S. P.
Murarka
,
M. H.
Read
,
C. J.
Doherty
, and
D. B.
Fraser
,
J. Electrochem. Soc.
129
,
293
(
1982
).
21.
V.
Malhotra
,
T. L.
Martin
, and
J. E.
Mahan
,
J. Vac. Sci. Technol. B
2
,
10
(
1984
).
22.
E.
Bucher
,
S.
Schulz
,
M. Ch.
Lux‐Steiner
,
P.
Munz
,
U.
Gubler
, and
F.
Greuter
,
Appl. Phys. A
40
,
71
(
1986
).
23.
F.
Nava
,
K. N.
Tu
,
E.
Mazzega
,
M.
Michelini
and
G.
Queirolo
,
J. Appl. Phys.
61
,
1085
(
1987
).
24.
F.
Nava
,
O.
Bisi
, and
K. N.
Tu
,
Phys. Rev. B
34
,
6143
(
1986
).
25.
M. Nakamura, S. Matsumoto, and T. Hirano, J. Mater. Sci. (in press).
26.
Ch.
Krontiras
,
I.
Suni
,
F. M.
d’Heurle
,
F. K.
LeGoues
, and
R.
Joshi
,
J. Phys. F
17
,
1953
(
1987
).
27.
F. A.
Sidorenko
,
P. V.
Geld
, and
M.
Shumilov
,
Fiz. Met. Metalloved.
9
,
861
(
1960
).
28.
G. V. Samsonov and I. M. Vinittski, Handbook of Refractory Compounds (Metallurgiya, Moscow, 1976; IFZ/Plenum, New York, 1980).
29.
F. A.
Sidorenko
,
P. V.
Geld
,
V. Ya.
Elner
, and
B. V.
Ryzhenko
,
J. Phys. Chem. Solids
43
,
297
(
1982
).
30.
See, for example,
M. R.
Cimberle
,
G.
Bobel
, and
C.
Rizzuto
,
Adv. Phys.
23
,
639
(
1974
).
31.
A. Kelly and G. W. Groves, Crystallography and Crystal Defects (Longman, London, 1970).
32.
A. G.
Balogh
,
L.
Bottyan
,
G.
Brauer
,
I.
Dezi
, and
B.
Molnar
,
J. Phys. F
16
,
1725
(
1986
).
33.
See, for example,
K. C. R.
Chiu
,
J. M.
Poate
,
L. C.
Feldman
, and
C. J.
Doherty
,
Appl. Phys. Lett.
36
,
544
(
1980
);
S.
Saitoh
,
H.
Ishiwara
, and
S.
Furukawa
,
Appl. Phys. Lett.
37
,
203
(
1980
); ,
Appl. Phys. Lett.
J. C.
Bean
and
J. M.
Poate
,
Appl. Phys. Lett.
37
,
643
(
1980
).,
Appl. Phys. Lett.
34.
J. C.
Hensel
,
R. T.
Tung
,
J. M.
Poate
, and
F. C.
Unterwald
,
Appl. Phys. Lett.
44
,
913
(
1984
).
35.
N. F. Mott and H. Jones, The Theory of the Properties of Metals and Alloys (Dover, New York, 1958).
36.
G. W.
Webb
,
Phys. Rev.
181
,
1127
(
1969
).
37.
F. J.
Pinski
,
P. B.
Allen
, and
W. H.
Butler
,
Phys. Rev.
23
,
5080
(
1981
).
38.
J. H.
Weaver
,
A.
Franciosi
, and
V. L.
Moruzzi
,
Phys. Rev. B
29
,
3923
(
1984
).
39.
W.
Speier
,
E. v.
Leuken
,
J. C.
Fuggle
,
D. D.
Sarma
,
L.
Kumar
,
B.
Danth
, and
K. H. J.
Buschow
,
Phys. Rev. B
39
,
6008
(
1989
).
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